Issue 22, 2010
From the journal:

Dalton Transactions

Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes†

Manuel Iglesiasa  and  Martin Albrecht*a  

* Corresponding authors

a School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland
E-mail: martin.albrecht@ucd.ie
Fax: (+)353-17162501

Abstract

Abnormal isoxazolylidene complexes, a new subclass of mesoionic complexes containing an isoxazolium-derived carbene type ligand, have been synthesised via oxidative addition and compared to structurally related mesoionic complexes by using 31P NMR spectroscopy as a convenient probe for their donor ability and in catalytic cross-coupling reactions.

Graphical abstract: Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

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Article information

DOI
https://doi.org/10.1039/C0DT00027B
Article type
Communication
Submitted
09 Dec 2009
Accepted
12 Mar 2010
First published
12 Apr 2010

Dalton Trans., 2010,39, 5213-5215

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Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

M. Iglesias and M. Albrecht, Dalton Trans., 2010, 39, 5213 DOI: 10.1039/C0DT00027B

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