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Issue 23, 2010
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Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

Miguel Rubio,a  Maxime A. Siegler,b  Anthony L. Spekb  and  Joost N. H. Reek*a 
Author affiliations

* Corresponding authors

a Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam, (The Netherlands)
E-mail: j.n.h.reek@uva.nl
Fax: +31 20 5255604
Tel: +31 20 5255265

b Bijvoet Center for Biomolecular Research, Utrecht, (The Netherlands)
E-mail: a.l.spek@uu.nl
Fax: +31 30 2533940
Tel: +31 30 2532538

Abstract

New coordination polymers based on different combinations of silver atoms and pyridyl-substituted N-heterocyclic carbene moieties are described. The addition of Zn(II) templates leads to Ag–Zn supramolecular assemblies via selective Zn⋯N interactions; a process that can be reverted.

Graphical abstract: Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

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Publication details

The article was received on 17 Feb 2010, accepted on 14 Apr 2010 and first published on 05 May 2010


Article type: Communication
DOI: 10.1039/C003352A
Citation: Dalton Trans., 2010,39, 5432-5435
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    Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

    M. Rubio, M. A. Siegler, A. L. Spek and J. N. H. Reek, Dalton Trans., 2010, 39, 5432
    DOI: 10.1039/C003352A

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