Correlating Pt–P bond lengths and Pt–P coupling constants

Paul G. Waddell; Alexandra M. Z. Slawin; J. Derek Woollins

doi:10.1039/C003256E

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Dalton Transactions

Issue 37, 2010

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Correlating Pt–P bond lengths and Pt–P coupling constants

Paul G. Waddell , Alexandra M. Z. Slawin and J. Derek Woollins

Dalton Trans., 2010,39, 8620-8625

DOI: 10.1039/C003256E
Received 16 Feb 2010, Accepted 08 Jun 2010
First published on the web 16 Aug 2010

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Abstract
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The X-ray structures of (5) cis-PtBr₂(P(OMe)₃)₂, (6) cis-PtBr₂(P(OMe)₂Ph)₂, (7) cis-PtBr₂(P(OMe)Ph₂)₂, (8) cis-PtBr₂(PPh₃)₂, (9) cis-PtI₂(P(OMe)₃)₂, (10) cis-PtI₂(P(OMe)₂Ph)₂, (11) cis-PtI₂(P(OMe)Ph₂)₂ and (12) cis-PtI₂(PPh₃)₂ are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt–P} varies linearly with the Pt–P bond length (l_Pt–P = 2.421 −J/24255) for these 12 complexes.