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The X-ray structures of (5) cis-PtBr2(P(OMe)3)2, (6) cis-PtBr2(P(OMe)2Ph)2, (7) cis-PtBr2(P(OMe)Ph2)2, (8) cis-PtBr2(PPh3)2, (9) cis-PtI2(P(OMe)3)2, (10) cis-PtI2(P(OMe)2Ph)2, (11) cis-PtI2(P(OMe)Ph2)2 and (12) cis-PtI2(PPh3)2 are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt–P} varies linearly with the Pt–P bond length (lPt–P = 2.421 −J/24255) for these 12 complexes.
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