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Issue 14, 2010
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New heterometallic [MnIII4LnIII4] wheels incorporating formate ligands

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Abstract

Two heteroctanuclear wheel complexes with an eight-membered saddle-like ring of [MnIII4LnIII4] (Ln = Dy, Gd), prepared by employing formates as key carboxylate bridges, exhibit antiferromagnetic interactions between MnIII and LnIII centers, and the wheel containing anisotropic DyIII ions shows SMM behaviour.

Graphical abstract: New heterometallic [MnIII4LnIII4] wheels incorporating formate ligands

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Publication details

The article was received on 21 Oct 2009, accepted on 09 Feb 2010 and first published on 26 Feb 2010


Article type: Communication
DOI: 10.1039/C000854K
Citation: Dalton Trans., 2010,39, 3375-3377
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    New heterometallic [MnIII4LnIII4] wheels incorporating formate ligands

    M. Li, A. M. Ako, Y. Lan, W. Wernsdorfer, G. Buth, C. E. Anson, A. K. Powell, Z. Wang and S. Gao, Dalton Trans., 2010, 39, 3375
    DOI: 10.1039/C000854K

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