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Issue 20, 2010
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Two-dimensional assembly of [MnIII2MnII2] single-molecule magnets and [Cu(pic)2] linking units (Hpic = picolinic acid)

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Abstract

In an attempt to develop novel coordination networks of SMMs, a Cu(II) picolinate complex has been used to coordinate ST = 9 tetranuclear Mn-based SMMs resulting in an intriguing 2D framework exhibiting a magnet-like behavior at low temperature.

Graphical abstract: Two-dimensional assembly of [MnIII2MnII2] single-molecule magnets and [Cu(pic)2] linking units (Hpic = picolinic acid)

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Publication details

The article was received on 07 Jan 2010, accepted on 10 Feb 2010 and first published on 01 Mar 2010


Article type: Communication
DOI: 10.1039/C000311E
Citation: Dalton Trans., 2010,39, 4744-4746
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    Two-dimensional assembly of [MnIII2MnII2] single-molecule magnets and [Cu(pic)2] linking units (Hpic = picolinic acid)

    I. Jeon, R. Ababei, L. Lecren, Y. Li, W. Wernsdorfer, O. Roubeau, C. Mathonière and R. Clérac, Dalton Trans., 2010, 39, 4744
    DOI: 10.1039/C000311E

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