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Issue 20, 2010
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Structure and magnetic properties of a decanuclear MnII2MnIII2Dy6 aggregate

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Abstract

Using glycerol (H3gly) as a primary ligand, the decanuclear aggregate [MnII2MnIII2DyIII63-OH)2(Hgly)4(H2gly)2(PhCO2)16(H2O)2]·10CH3CN (1) has been synthesised; it has a structure built up from two Mn2Dy2 heterocubane units linked through a central Dy2(μ-benzoate)4 paddle-wheel dimer and shows slow relaxation of its magnetisation.

Graphical abstract: Structure and magnetic properties of a decanuclear MnII2MnIII2Dy6 aggregate

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Publication details

The article was received on 06 Jan 2010, accepted on 04 Feb 2010 and first published on 12 Feb 2010


Article type: Communication
DOI: 10.1039/C000082E
Citation: Dalton Trans., 2010,39, 4740-4743
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    Structure and magnetic properties of a decanuclear MnII2MnIII2Dy6 aggregate

    Z. Majeed, K. C. Mondal, G. E. Kostakis, Y. Lan, C. E. Anson and A. K. Powell, Dalton Trans., 2010, 39, 4740
    DOI: 10.1039/C000082E

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