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Issue 20, 2010
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Novel mixed-valent CoII2CoIII4LnIII4 aggregates with ligands derived from tris-(hydroxymethyl)aminomethane (Tris)

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Abstract

Isostructural CoII2CoIII4LnIII4 (Ln = Y (1), Gd (2) and Dy (3)) coordination clusters formed using the ligand Tris are the first examples of 3d-4f complexes involving this ligand and show weak ferromagnetic coupling between the CoII ions and slow relaxation (SMM) behaviour for 3.

Graphical abstract: Novel mixed-valent CoII2CoIII4LnIII4 aggregates with ligands derived from tris-(hydroxymethyl)aminomethane (Tris)

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Publication details

The article was received on 06 Jan 2010, accepted on 17 Feb 2010 and first published on 02 Mar 2010


Article type: Communication
DOI: 10.1039/C000008F
Citation: Dalton Trans., 2010,39, 4737-4739
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    Novel mixed-valent CoII2CoIII4LnIII4 aggregates with ligands derived from tris-(hydroxymethyl)aminomethane (Tris)

    H. Xiang, Y. Lan, H. Li, L. Jiang, T. Lu, C. E. Anson and A. K. Powell, Dalton Trans., 2010, 39, 4737
    DOI: 10.1039/C000008F

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