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Issue 20, 2010
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Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

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Abstract

Enantiomeric, ferromagnetically coupled decanuclear {Ni6Fe4} cages with adamantane-like cores were synthesized around templating tetraethylammonium cations, as shown by crystallographic analysis and CSI-MS, and their homochiral nature was confirmed by circular dichroism measurements.

Graphical abstract: Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

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Publication details

The article was received on 02 Dec 2009, accepted on 08 Jan 2010 and first published on 21 Jan 2010


Article type: Communication
DOI: 10.1039/B925399H
Citation: Dalton Trans., 2010,39, 4730-4733
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    Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

    T. Shiga, G. N. Newton, J. S. Mathieson, T. Tetsuka, M. Nihei, L. Cronin and H. Oshio, Dalton Trans., 2010, 39, 4730
    DOI: 10.1039/B925399H

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