Unexpected chemoselectivity in the Schiff condensation of amines with η2(C,O)- η1(O)-coordinated aldehyde

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Dalton Transactions

Issue 5, 2010

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Celedonio M. Álvarez , Raúl García-Rodríguez , Jose M. Martín-Alvarez and Daniel Miguel

Dalton Trans., 2010, 39, 1201-1203

DOI: 10.1039/B921892K
Received 19 Oct 2009, Accepted 30 Oct 2009
First published on the web 17 Nov 2009

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The aldehyde function coordinated as η¹; η² is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.

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