Markedly different cytotoxicity of the two enantiomers of C2-symmetrical Ti(IV) phenolato complexes; mechanistic implications

Cesar M. Manna; Edit Y. Tshuva

doi:10.1039/B920786B

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Dalton Transactions

Issue 5, 2010

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Markedly different cytotoxicity of the two enantiomers of C₂-symmetrical Ti(IV) phenolato complexes; mechanistic implications

Cesar M. Manna and Edit Y. Tshuva

Dalton Trans., 2010, 39, 1182-1184

DOI: 10.1039/B920786B
Received 29 Jun 2009, Accepted 16 Oct 2009
First published on the web 02 Nov 2009

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The two enantiomers of a member of the highly active C₂-symmetrical bis(isopropoxo) Ti(IV) family of complexes of diamine bis(phenolato) ligands demonstrate markedly different cytotoxicity, supporting a chiral biological target of activity and participation of a ligand-bound active species.

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Dalton Transactions

Markedly different cytotoxicity of the two enantiomers of C₂-symmetrical Ti(IV) phenolato complexes; mechanistic implications

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