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Issue 15, 2010
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Steric and electronic effects in metallophilic double salts

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Abstract

This Perspective highlights our efforts to assemble infinite chains of metal atoms in double salts of the form [M]+[M] under the complementary influences of metallophilic interactions and electrostatic attraction. Our design strategy necessarily incorporates the significant steric constraints of one-dimensional assemblies as well as the more subtle and challenging electronic tuning of weak dispersion forces.

Graphical abstract: Steric and electronic effects in metallophilic double salts

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Publication details

The article was received on 05 Oct 2009, accepted on 17 Dec 2009 and first published on 28 Jan 2010


Article type: Perspective
DOI: 10.1039/B920389C
Citation: Dalton Trans., 2010,39, 3543-3553
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    Steric and electronic effects in metallophilic double salts

    L. H. Doerrer, Dalton Trans., 2010, 39, 3543
    DOI: 10.1039/B920389C

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