Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

Lesley C. Lewis-Alleyne; Makeba B. Murphy-Jolly; Xavier F. Le Goff; Andrew J. M. Caffyn

doi:10.1039/B918348E

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Dalton Transactions

Issue 5, 2010

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Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

Lesley C. Lewis-Alleyne , Makeba B. Murphy-Jolly , Xavier F. Le Goff and Andrew J. M. Caffyn

Dalton Trans., 2010, 39, 1198-1200

DOI: 10.1039/B918348E
Received 07 Sep 2009, Accepted 26 Oct 2009
First published on the web 11 Nov 2009

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Abstract
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We report a one-step synthesis of the phosphine, PPh₂ⁱC₃F₇ from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)₅PPh₂ⁱC₃F₇ was synthesised and the synthesis and structure of trans-PtCl₂(PPh₂ⁱC₃F₇)₂ are described. PPh₂ⁱC₃F₇ was found to be a bulky electron-withdrawing ligand.

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Dalton Transactions

Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

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