New alkylzinc complexes with bulky tris(triazolyl)borate ligands: Surprising water stability and reactivity

Mukesh Kumar; Elizabeth T. Papish; Matthias Zeller; Allen D. Hunter

doi:10.1039/B918328K

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Dalton Transactions

Issue 1, 2010

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New alkylzinc complexes with bulky tris(triazolyl)borate ligands: Surprising water stability and reactivity

Mukesh Kumar , Elizabeth T. Papish , Matthias Zeller and Allen D. Hunter

Dalton Trans., 2010, 39, 59-61

DOI: 10.1039/B918328K
Received 11 Sep 2009, Accepted 14 Oct 2009
First published on the web 27 Oct 2009

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Abstract
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Bulky alkylzinc complexes, (Ttz^tBu,Me)ZnMe and (Ttz^tBu,Me)ZnEt, show remarkable stability towards water and both complexes crystallize with one molecule of adventitious water hydrogen bonded to two triazole rings; in contrast the less bulky complex, (Ttz^Ph,Me)ZnEt, reacts with water to yield (Ttz^Ph,Me)₂Zn.

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Experimental details and spectral data for all newcompounds
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Dalton Transactions

New alkylzinc complexes with bulky tris(triazolyl)borate ligands: Surprising water stability and reactivity

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