A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state

Miguel Martínez-Calvo; Ana M. González-Noya; Rosa Pedrido; María J. Romero; M. Isabel Fernández; Guillermo Zaragoza; Manuel R. Bermejo

doi:10.1039/B915953C

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Dalton Transactions

Issue 5, 2010

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A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state

Miguel Martínez-Calvo , Ana M. González-Noya , Rosa Pedrido , María J. Romero , M. Isabel Fernández , Guillermo Zaragoza and Manuel R. Bermejo

Dalton Trans., 2010, 39, 1191-1194

DOI: 10.1039/B915953C
Received 04 Aug 2009, Accepted 24 Oct 2009
First published on the web 10 Nov 2009
This article is part of the collection: FIGIPAS 2009

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Abstract
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A [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains.

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Supplementary Info

Fig. S1 ¹¹³Cd NMR spectrum for 1 and Fig. S2 Fluorescence emission spectrum for 1
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Crystal structure data
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Articles By

Miguel Martínez-Calvo
Ana M. González-Noya
Rosa Pedrido
María J. Romero
M. Isabel Fernández
Guillermo Zaragoza
Manuel R. Bermejo

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Dalton Transactions

A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state

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