Olefin metathesis as a tool for multinuclear Co(III)salen catalyst construction: access to cooperative catalysts

Robert M. Haak; Marta Martínez Belmonte; Eduardo C. Escudero-Adán; Jordi Benet-Buchholz; Arjan W. Kleij

doi:10.1039/B911856J

skip RSC | ChemSpider | Feedback

Home > Journals > Dalton Transactions > Olefin metathesis as a ...

Authors & Referees | Librarians

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Dalton Transactions

Issue 2, 2010

More about this Journal
Editorial Board
Submit an Article

Follow Journal | |

Journal Home | RSC Journals

Paper

Previous Article | Next Article

Olefin metathesis as a tool for multinuclear Co(III)salen catalyst construction: access to cooperative catalysts

Robert M. Haak , Marta Martínez Belmonte , Eduardo C. Escudero-Adán , Jordi Benet-Buchholz and Arjan W. Kleij

Dalton Trans., 2010, 39, 593-602

DOI: 10.1039/B911856J
Received 17 Jun 2009, Accepted 30 Oct 2009
First published on the web 12 Nov 2009
This article is part of the collection: New Talent: Inspiration for the future

Please wait while Download options loads

Request Permissions

Abstract
Cited by
Compounds
Related Content

The construction of novel (macrocyclic) multinuclear Co(III)salen catalysts is reported. Olefin metathesis has been used as a key construction tool for the multimetallic structures starting from versatile allyl-substituted salen scaffolds. The Co(III) complexes were tested in the hydrolytic kinetic resolution of (rac)-1,2-epoxyhexane and epoxide ring opening reactions using methanol as the nucleophile. The preliminary results suggest a cooperative mode of catalysis in the case of bis-Co(III)salen macrocycle 10.

This may take some time to load.

Supplementary Info

Copies of relevant spectra and crystallographic comments andGC/HPLC methods
PDF (1797K)
Crystal structure data
TXT (56K)

Articles By

Robert M. Haak
Marta Martínez Belmonte
Eduardo C. Escudero-Adán
Jordi Benet-Buchholz
Arjan W. Kleij

Terms & Conditions|Privacy |Accessibility|ACAP Enabled

Dalton Transactions

Olefin metathesis as a tool for multinuclear Co(III)salen catalyst construction: access to cooperative catalysts

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Articles By