On the mechanism of reduction of maleate and fumarate by NiI(1,4,8,11-tetraazacyclotetradecane)+ in aqueous solutions

Hava Rasnoshik; Alexandra Masarwa; Haim Cohen; Israel Zilbermann; Eric Maimon; Dan Meyerstein

doi:10.1039/B911725C

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Dalton Transactions

Issue 3, 2010

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On the mechanism of reduction of maleate and fumarate by Ni^I(1,4,8,11-tetraazacyclotetradecane)⁺ in aqueous solutions

Hava Rasnoshik , Alexandra Masarwa , Haim Cohen , Israel Zilbermann , Eric Maimon and Dan Meyerstein

Dalton Trans., 2010, 39, 823-833

DOI: 10.1039/B911725C
Received 16 Jun 2009, Accepted 11 Sep 2009
First published on the web 17 Nov 2009

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Ni^I(1,4,8,11-tetraazacyclotetradecane)⁺, Ni(I)L⁺, was produced in neutral aqueous solutions by radiolytic techniques. The mechanism and kinetics of the reaction of Ni(I)L⁺ with maleate and fumarate were studied applying pulse-radiolysis and analysis of the final products. Surprisingly the mechanisms of reduction of maleate and fumarate differ considerably. Based on the results it was also shown that Ni(II)L²⁺ is an electrocatalyst for the reduction of alkenes in aqueous solutions.

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Hava Rasnoshik
Alexandra Masarwa
Haim Cohen
Israel Zilbermann
Eric Maimon
Dan Meyerstein

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Dalton Transactions

On the mechanism of reduction of maleate and fumarate by Ni^I(1,4,8,11-tetraazacyclotetradecane)⁺ in aqueous solutions

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