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Issue 19, 2010
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Self-assembly of polyoxoselenitopalladate nanostars [Pd153-SeO3)103-O)10Na]9− and their supramolecular pairing in the solid state

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Abstract

An anionic Pd15-oxo-cluster [Pd153-SeO3)103-O)10Na]9− has been synthesized. It is the result of an unprecedented self-assembly of Pd2+ and Na+ cations, SeO32− and oxo anions. It has been found for the first time, that selenito groups can give rise to supramolecular interactions in the solid state with palladium atoms, through the selenium electron lone pairs.

Graphical abstract: Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state

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Publication details

The article was received on 12 Jan 2010, accepted on 29 Mar 2010 and first published on 17 Apr 2010


Article type: Communication
DOI: 10.1039/B927537A
Citation: Dalton Trans., 2010,39, 4479-4481
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    Self-assembly of polyoxoselenitopalladate nanostars [Pd153-SeO3)103-O)10Na]9− and their supramolecular pairing in the solid state

    M. Delferro, C. Graiff, L. Elviri and G. Predieri, Dalton Trans., 2010, 39, 4479
    DOI: 10.1039/B927537A

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