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Issue 5, 2010
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Kinetic and structural studies on ‘tethered’ Ru(II) arene ketone reduction catalysts

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Abstract

A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using 1H NMR spectroscopy.

Graphical abstract: Kinetic and structural studies on ‘tethered’ Ru(ii) arene ketone reduction catalysts

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Publication details

The article was received on 04 Aug 2009, accepted on 27 Oct 2009 and first published on 01 Dec 2009


Article type: Paper
DOI: 10.1039/B915932K
Citation: Dalton Trans., 2010,39, 1395-1402
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    Kinetic and structural studies on ‘tethered’ Ru(II) arene ketone reduction catalysts

    F. K. (. Cheung, A. J. Clarke, G. J. Clarkson, D. J. Fox, M. A. Graham, C. Lin, A. L. Crivillé and M. Wills, Dalton Trans., 2010, 39, 1395
    DOI: 10.1039/B915932K

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