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Issue 42, 2010
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Gas-phase isolation of diethyl guanosine 5′-monophosphate and its conformational assignment

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Abstract

We show that intact neutral molecules of guanosine 5′-monophosphate can be vaporized by laser desorption when its phosphate group is esterified. The UV and IR spectroscopic measurements of this nucleotide reveal the existence of a novel internal hydrogen-bonding conformation of the phosphate group and guanine moiety.

Graphical abstract: Gas-phase isolation of diethyl guanosine 5′-monophosphate and its conformational assignment

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Publication details

The article was received on 07 Jul 2010, accepted on 31 Aug 2010 and first published on 22 Sep 2010


Article type: Communication
DOI: 10.1039/C0CP01105C
Citation: Phys. Chem. Chem. Phys., 2010,12, 13918-13921
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    Gas-phase isolation of diethyl guanosine 5′-monophosphate and its conformational assignment

    H. Asami, M. Tsukamoto, Y. Hayakawa and H. Saigusa, Phys. Chem. Chem. Phys., 2010, 12, 13918
    DOI: 10.1039/C0CP01105C

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