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Issue 44, 2010
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A comparative MD study of the local structure of polymer semiconductors P3HT and PBTTT

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Abstract

Atomistic molecular dynamics simulations of P3HT and PBTTT-C12 at finite temperatures are carried out to investigate the nanoscale structural properties that lead to higher measured hole mobility in PBTTT versus P3HT field-effect transistors. Simulations of the polymer melts show that the structural properties in PBTTT facilitate both intra- and inter-chain charge transport compared with P3HT due to a greater degree of planarity, closer and more parallel stacking of the thiophene and thienothiophene rings, and possible interdigitation of the dodecyl side chains. The crucial role played by the bulky dodecyl side chain and thienothiophene ring, respectively, in determining intra-chain and inter-chain structural order is clarified.

Graphical abstract: A comparative MD study of the local structure of polymer semiconductors P3HT and PBTTT

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Publication details

The article was received on 03 Jun 2010, accepted on 26 Aug 2010 and first published on 23 Sep 2010


Article type: Paper
DOI: 10.1039/C0CP00785D
Citation: Phys. Chem. Chem. Phys., 2010,12, 14735-14739
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    A comparative MD study of the local structure of polymer semiconductors P3HT and PBTTT

    K. Do, D. M. Huang, R. Faller and A. J. Moulé, Phys. Chem. Chem. Phys., 2010, 12, 14735
    DOI: 10.1039/C0CP00785D

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