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Issue 32, 2010
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Measurement of hetero-nuclear distances using a symmetry-based pulse sequence in solid-state NMR

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Abstract

A Symmetry-based Resonance-Echo DOuble-Resonance (S-REDOR) method is proposed for measuring hetero-nuclear dipolar couplings between two different spin-1/2 nuclei, under fast magic-angle spinning. The hetero-nuclear dipolar couplings are restored by employing the SR421 sequence, which requires the rf-field strength to be only twice the spinning frequency. The S-REDOR experiment is extended to S-RESPDOR (Symmetry-based Resonance-Echo Saturation-Pulse DOuble-Resonance) for determining dipolar coupling between a spin-1/2 nucleus (e.g.13C) and 14N. It is demonstrated that S-REDOR and S-RESPDOR methods suppress efficiently the homo-nuclear dipolar interaction of the irradiated nucleus and benefit from high robustness to the rf-field inhomogeneity, chemical shielding and dipolar truncation. Therefore, these methods allow the measurement of 13C/14,15N distances, with 13C observation, in uniformly 13C-labeled samples. Furthermore, we provide analytical solutions for the S-REDOR and S-RESPDOR dephasing curves. These solutions facilitate the measurement of hetero-nuclear distances from experimental data.

Graphical abstract: Measurement of hetero-nuclear distances using a symmetry-based pulse sequence in solid-state NMR

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Publication details

The article was received on 15 Dec 2009, accepted on 12 Apr 2010 and first published on 24 Jun 2010


Article type: Paper
DOI: 10.1039/B926546E
Citation: Phys. Chem. Chem. Phys., 2010,12, 9395-9405
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    Measurement of hetero-nuclear distances using a symmetry-based pulse sequence in solid-state NMR

    L. Chen, Q. Wang, B. Hu, O. Lafon, J. Trébosc, F. Deng and J. Amoureux, Phys. Chem. Chem. Phys., 2010, 12, 9395
    DOI: 10.1039/B926546E

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