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Issue 20, 2010
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Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

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Abstract

A mechanism of H2 uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous δ phase. An ordered arrangement of the H2 molecules is proven by FTIR spectra while the inclusion of H2 is assessed by gravimetric measurements and molecular simulations.

Graphical abstract: Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

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Publication details

The article was received on 04 Nov 2009, accepted on 03 Mar 2010 and first published on 08 Apr 2010


Article type: Paper
DOI: 10.1039/B923173K
Citation: Phys. Chem. Chem. Phys., 2010,12, 5369-5374
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    Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

    S. Figueroa-Gerstenmaier, C. Daniel, G. Milano, G. Guerra, O. Zavorotynska, J. G. Vitillo, A. Zecchina and G. Spoto, Phys. Chem. Chem. Phys., 2010, 12, 5369
    DOI: 10.1039/B923173K

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