Electrical conductivity in patterned silver–mesoporous titania nanocomposite thin films: towards robust 3D nano-electrodes

Eduardo D. Martínez; Leticia Granja; Martín G. Bellino; Galo J. A. A. Soler-Illia

doi:10.1039/C0CP00824A

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Physical Chemistry Chemical Physics

Issue 43, 2010

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Electrical conductivity in patterned silver–mesoporous titania nanocomposite thin films: towards robust 3D nano-electrodes

Eduardo D. Martínez,^a Leticia Granja,^b Martín G. Bellino^a and Galo J. A. A. Soler-Illia*^a

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Gerencia de Química, CNEA, CAC, Av., Gral Paz 1499, San Martín B1650KNA, Argentina
E-mail: gsoler@cnea.gov.ar

Departamento de Materia Condensada, Gerencia de Investigación y Aplicaciones, CNEA, CAC, Buenos Aires, Argentina

Phys. Chem. Chem. Phys., 2010,12, 14445-14448

DOI: 10.1039/C0CP00824A
Received 08 Jun 2010, Accepted 03 Sep 2010
First published online 01 Oct 2010

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Abstract
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The space-resolved electrical conductivity of patterned silver nanoparticle (NP) arrays embedded in mesoporous TiO₂ thin films was locally evaluated using a conductive-tip AFM. A remarkable conductivity dependence on the film mesostructure and metal NP loading was observed, confirming a three-dimensional current flow throughout the nanocomposite.

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Detailed film preparation and characterization, including pore filling assessment.
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