Issue 11, 2010
From the journal:

CrystEngComm

Anion-directed genuine meso-helical supramolecular isomers of two 1D Ag(i) complexes based on arene-linked bis(pyrazolyl)methane ligands†

Shuang Wang,a   Hongying Zang,a   Chunyi Sun,a   Guangjuan Xu,a   Xinlong Wang,*a   Kuizhan Shao,a   Yaqian Lana  and  Zhongmin Su*a  

* Corresponding authors

a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, P. R. China
E-mail: zmsu@nenu.edu.cn

Abstract

Two genuine supramolecular isomers (Lp = p-[CH(pz)2]2C6H4), have been successfully obtained under similar solvothermal conditions by the reaction of arene-linked p-bis[bis(1-pyrazolyl)methyl]benzene ligand with AgNO3. Both of the compounds are made of unusual meso-helical chains and present a three-dimensional (3D) supramolecular structure. Compounds 1 and 2 were characterized by elemental analyses, IR spectra, single-crystal X-ray diffraction and thermogravimetric (TG) analyses. The fluorescence property of them has also been studied.

Graphical abstract: Anion-directed genuine meso-helical supramolecular isomers of two 1D Ag(i) complexes based on arene-linked bis(pyrazolyl)methane ligands

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Article information

DOI
https://doi.org/10.1039/C0CE00137F
Article type
Communication
Submitted
27 Apr 2010
Accepted
13 Jun 2010
First published
06 Jul 2010

CrystEngComm, 2010,12, 3458-3462

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Anion-directed genuine meso-helical supramolecular isomers of two 1D Ag(I) complexes based on arene-linked bis(pyrazolyl)methane ligands

S. Wang, H. Zang, C. Sun, G. Xu, X. Wang, K. Shao, Y. Lan and Z. Su, CrystEngComm, 2010, 12, 3458 DOI: 10.1039/C0CE00137F

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