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Issue 1, 2010
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Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell

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Abstract

Solvothermal treatment of copper halides and 3-amino-5-mercapto-1,2,4-triazole (H2amtz) produced three isostructural complexes [Cu31X4(H1.55amtz)24](SO4)8·xDMF [X = Cl, Br and I, x ∼ 32], which show 3-D networks with bor topology constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell.

Graphical abstract: Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell

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Publication details

The article was received on 02 Sep 2009, accepted on 16 Sep 2009 and first published on 25 Sep 2009


Article type: Communication
DOI: 10.1039/B918159H
Citation: CrystEngComm, 2010,12, 55-58
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    Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell

    Z. Hao, C. Guo, H. Wu and X. Zhang, CrystEngComm, 2010, 12, 55
    DOI: 10.1039/B918159H

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