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Issue 47, 2010
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Assembly of the Audiphosphine helical cage molecules via alkynylμ4-methylydine ligand transformation

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Abstract

The assembly of the gold(I)diphosphine cages occurs via unprecedented transformation of the alkynyls into the μ4-methylydine ligands under basic conditions. These compounds demonstrate the equilibrium between the PM helical isomers and serve as hosts to accommodate small molecules (CH2Cl2 and CS2).

Graphical abstract: Assembly of the Au–diphosphine helical cage molecules via alkynyl–μ4-methylydine ligand transformation

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Publication details

The article was received on 18 Sep 2010, accepted on 13 Oct 2010 and first published on 01 Nov 2010


Article type: Communication
DOI: 10.1039/C0CC03953E
Citation: Chem. Commun., 2010,46, 8926-8928
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    Assembly of the Audiphosphine helical cage molecules via alkynylμ4-methylydine ligand transformation

    I. O. Koshevoy, M. Haukka, S. I. Selivanov, S. P. Tunik and T. A. Pakkanen, Chem. Commun., 2010, 46, 8926
    DOI: 10.1039/C0CC03953E

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