A new class of rhodamine luminophores: design, syntheses and aggregation-induced emission enhancement

Shinichiro Kamino; Yuka Horio; Seiji Komeda; Katsuhiko Minoura; Hayato Ichikawa; Jun Horigome; Asana Tatsumi; Shinya Kaji; Takako Yamaguchi; Yoshihide Usami; Shun Hirota; Shuichi Enomoto; Yoshikazu Fujita

doi:10.1039/C0CC03407J

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Chemical Communications

Issue 47, 2010

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A new class of rhodamine luminophores: design, syntheses and aggregation-induced emission enhancement

Shinichiro Kamino,*^a^b Yuka Horio,^c Seiji Komeda,^d Katsuhiko Minoura,^c Hayato Ichikawa,^e Jun Horigome,^f Asana Tatsumi,^b Shinya Kaji,^c Takako Yamaguchi,^c Yoshihide Usami,^c Shun Hirota,^g Shuichi Enomoto^a^b and Yoshikazu Fujita^c

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Laboratory of Multiple Molecular Imaging Research Center for Molecular Imaging Science RIKEN Kobe Institute, Kobe, Japan

Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University, Okayama, Japan
E-mail: skamino@riken.jp ;
Fax: +81 862517953 ;
Tel: +81 862517952

Osaka University of Pharmaceutical Sciences, Takatsuki, Japan

Suzuka University of Medical Science, Suzuka, Japan

College of Industrial Technology, Nihon University, Narashino, Japan

Hitachi High-Technologies Co., Ltd., Hitachinaka, Japan

Nara Institute of Science and Technology, Ikoma, Japan

Chem. Commun., 2010,46, 9013-9015

DOI: 10.1039/C0CC03407J
Received 23 Aug 2010, Accepted 20 Oct 2010
First published online 05 Nov 2010

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A new class of rhodamine luminophores, 3′,3″-bis(oxospiroisobenzofuran)-3,7-bis(dialkylamino)benzopyrano-xanthene derivatives (ABPX), have been successfully developed. The emission behavior of ABPX series is directly opposite to the concentration quenching of conventional rhodamine dyes. ABPX series exhibit aggregation-induced emission enhancement (AIEE).

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