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Issue 47, 2010
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Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

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Abstract

The introduction of fluorinated aryls at zinc in Zn4N8-type (and to a lesser extent Zn4N6O) cages led to enhanced H2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.

Graphical abstract: Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

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Publication details

The article was received on 20 Aug 2010, accepted on 12 Oct 2010 and first published on 03 Nov 2010


Article type: Communication
DOI: 10.1039/C0CC03380D
Citation: Chem. Commun., 2010,46, 9055-9057
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    Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

    C. Redshaw, S. Jana, C. Shang, M. R. J. Elsegood, X. Lu and Z. X. Guo, Chem. Commun., 2010, 46, 9055
    DOI: 10.1039/C0CC03380D

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