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Issue 43, 2010
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Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

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Abstract

We show that a redox active {Fe4S4}2+cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Graphical abstract: Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

  • This article is part of the themed collection: Hydrogen
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Publication details

The article was received on 02 Aug 2010, accepted on 07 Sep 2010 and first published on 05 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC02962A
Citation: Chem. Commun., 2010,46, 8189-8191
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    Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

    S. Ibrahim, P. M. Woi, Y. Alias and C. J. Pickett, Chem. Commun., 2010, 46, 8189
    DOI: 10.1039/C0CC02962A

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