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Issue 41, 2010
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Synthesis, structural and magnetic studies of an isostructural family of mixed 3d/4f tetranuclear ‘star’ clusters

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Abstract

DC magnetic studies on new ‘star’ clusters of formula [Mn3Ln(acac)6(tea)2][Mn(acac)3] (Ln = Gd (1) and Dy (2)) and [Fe3Ln(acac)6(tea)2] (Ln = Gd (3) and Dy (4)) show that all cases display weak coupling, with compounds 3 and 4 displaying ferromagnetic JLnFe coupling, 3 having a S = 11 ground state.

Graphical abstract: Synthesis, structural and magnetic studies of an isostructural family of mixed 3d/4f tetranuclear ‘star’ clusters

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Publication details

The article was received on 18 Jul 2010, accepted on 18 Aug 2010 and first published on 20 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02642E
Citation: Chem. Commun., 2010,46, 7787-7789
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    Synthesis, structural and magnetic studies of an isostructural family of mixed 3d/4f tetranuclear ‘star’ clusters

    N. F. Chilton, S. K. Langley, B. Moubaraki and K. S. Murray, Chem. Commun., 2010, 46, 7787
    DOI: 10.1039/C0CC02642E

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