Jump to main content
Jump to site search

Issue 42, 2010
Previous Article Next Article

FeIII/FeII regular charge order in metal–organic framework

Author affiliations

Abstract

The hydrolysis of the DMF solvent (DMF = N,N′-dimethylformamide) generates in situ the template cations DMA+ (dimethylammonium cation): it leads to the first MOF type solid FeIII0.5FeII0.5(OH,F)(O2C–C6H4–CO2)·0.5DMA with a regular charge order FeIII/FeII and an anionic framework with pores filled by counter-cations which behaves as a quasi-1D AF system with alternate localized FeII and FeIII moments.

Graphical abstract: FeIII/FeII regular charge order in metal–organic framework

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 28 Jun 2010, accepted on 07 Sep 2010 and first published on 23 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02161J
Citation: Chem. Commun., 2010,46, 7987-7989
  •   Request permissions

    FeIII/FeII regular charge order in metal–organic framework

    M. E. Medina, Y. Dumont, J. Grenèche and F. Millange, Chem. Commun., 2010, 46, 7987
    DOI: 10.1039/C0CC02161J

Search articles by author