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Issue 41, 2010
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The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN[double bond, length as m-dash])Mo(H)(PMe3)

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Abstract

Complex (Cp)(ArN[double bond, length as m-dash])Mo(H)(PMe3) (2, Ar = 2,6-diisopropylphenyl) catalyzes the hydrosilylation of carbonyls by an unexpected associative mechanism. Complex 2 also reacts with PhSiH3 by a σ-bond metathesis mechanism to give the silyl derivative (Cp)(ArN[double bond, length as m-dash])Mo(SiH2Ph)(PMe3).

Graphical abstract: The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN [[double bond, length as m-dash]] )Mo(H)(PMe3)

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Publication details

The article was received on 11 Jun 2010, accepted on 02 Sep 2010 and first published on 21 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC01850C
Citation: Chem. Commun., 2010,46, 7831-7833
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    The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN[double bond, length as m-dash])Mo(H)(PMe3)

    O. G. Shirobokov, S. I. Gorelsky, R. Simionescu, L. G. Kuzmina and G. I. Nikonov, Chem. Commun., 2010, 46, 7831
    DOI: 10.1039/C0CC01850C

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