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Issue 43, 2010
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Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

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Abstract

Ru-TsDPEN confined in the nanocage with an amphiphilic microenvironment can be ten times more active than that with a hydrophobic one in the transfer hydrogenation of acetophenone in HCOONa–H2O, which is mainly due to the enhanced diffusion rates of reactants during the catalytic process.

Graphical abstract: Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

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Publication details

The article was received on 14 May 2010, accepted on 25 Jun 2010 and first published on 13 Jul 2010


Article type: Communication
DOI: 10.1039/C0CC01401J
Citation: Chem. Commun., 2010,46, 8145-8147
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    Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

    S. Bai, H. Yang, P. Wang, J. Gao, B. Li, Q. Yang and C. Li, Chem. Commun., 2010, 46, 8145
    DOI: 10.1039/C0CC01401J

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