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Issue 31, 2010
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Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

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Abstract

The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I2 and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and η2-coordination to Zr. Addition of H2 leads to both oxidative addition across the M–M bond and P–N bond cleavage.

Graphical abstract: Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

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Publication details

The article was received on 07 May 2010, accepted on 10 Jun 2010 and first published on 24 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC01272F
Citation: Chem. Commun., 2010,46, 5790-5792
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    Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

    C. M. Thomas, J. W. Napoline, G. T. Rowe and B. M. Foxman, Chem. Commun., 2010, 46, 5790
    DOI: 10.1039/C0CC01272F

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