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Issue 35, 2010
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Solid–liquid interface synthesis of microcrystalline porous coordination networks

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Abstract

Solid–liquid interface synthesis provided a unique way to selectively and efficiently prepare molecular complexes (ML2) and metastable porous coordination networks in short crystallization times. In sharp contrast, their solution reactions gave interpenetrated open-framework networks. We succeeded in solving a crystal structure of the metastable network by ab initio powder X-ray analysis.

Graphical abstract: Solid–liquid interface synthesis of microcrystalline porous coordination networks

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Publication details

The article was received on 27 Apr 2010, accepted on 20 Jul 2010 and first published on 10 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC01141J
Citation: Chem. Commun., 2010,46, 6515-6517
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    Solid–liquid interface synthesis of microcrystalline porous coordination networks

    J. Martí-Rujas, Y. Matsushita, F. Izumi, M. Fujita and M. Kawano, Chem. Commun., 2010, 46, 6515
    DOI: 10.1039/C0CC01141J

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