Issue 30, 2010
From the journal:

Chemical Communications

Copper-catalyzed one-pot synthesis of α-functionalized imidates†

Ralph Husmann,a   Yun S. Na,b   Carsten Bolm*a  and  Sukbok Chang*b  

* Corresponding authors

a Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: carsten.bolm@oc.rwth-aachen.de
Fax: +49 241 8092391
Tel: +49 241 8094675

b Department of Chemistry and Molecular-Level Interface Research Center, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
E-mail: sbchang@kaist.ac.kr
Fax: +82 42 350 2810
Tel: +82 42 350 2841

Abstract

A four-component, one-pot procedure gives access to α-functionalized imidates starting from readily available terminal alkynes, sulfonyl azides, alcohols and nitroalkenes using a copper catalyst and triethylamine as a base under mild conditions.

Graphical abstract: Copper-catalyzed one-pot synthesis of α-functionalized imidates

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Article information

DOI
https://doi.org/10.1039/C0CC00941E
Article type
Communication
Submitted
14 Apr 2010
Accepted
24 May 2010
First published
24 Jun 2010

Chem. Commun., 2010,46, 5494-5496

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Copper-catalyzed one-pot synthesis of α-functionalized imidates

R. Husmann, Y. S. Na, C. Bolm and S. Chang, Chem. Commun., 2010, 46, 5494 DOI: 10.1039/C0CC00941E

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