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Issue 24, 2010
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Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)

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Abstract

The homoleptic cations [M(PMe3)5]+ (M = Rh, Ir) are formed in high yield from reactions of 16 electron 4 coordinate precursors, such as [Rh(PMe3)4]+, with excess neat PMe3 at 80 °C.

Graphical abstract: Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)

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Publication details

The article was received on 13 Apr 2010, accepted on 06 May 2010 and first published on 14 May 2010


Article type: Communication
DOI: 10.1039/C0CC00892C
Citation: Chem. Commun., 2010,46, 4300-4302
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    Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)

    J. H. Rivers and R. A. Jones, Chem. Commun., 2010, 46, 4300
    DOI: 10.1039/C0CC00892C

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