Directed self-assembly of a ring-in-ring complex

Ross S. Forgan; Douglas C. Friedman; Charlotte L. Stern; Carson J. Bruns; J. Fraser Stoddart

doi:10.1039/C0CC00776E

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Chemical Communications

Issue 32, 2010

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Directed self-assembly of a ring-in-ring complex

Ross S. Forgan , Douglas C. Friedman , Charlotte L. Stern , Carson J. Bruns and J. Fraser Stoddart

Chem. Commun., 2010, 46, 5861-5863

DOI: 10.1039/C0CC00776E
Received 05 Apr 2010, Accepted 26 Apr 2010
First published on the web 28 May 2010

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Abstract
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A strategic modification to the corner ligands in Pd^II-containing, electron-poor cyclophanes has profound repercussions for their assemblies with electron-rich aromatic crown ethers in both the solid and solution states; the formation of ring-in-ring complexes can override competing [3]catenane production on masking the hydrogen bond donor capabilities of the corner ligands.

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Synthesis, crystal structure data and detailed NMR analysis
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Articles By

Ross S. Forgan
Douglas C. Friedman
Charlotte L. Stern
Carson J. Bruns
J. Fraser Stoddart

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Chemical Communications

Directed self-assembly of a ring-in-ring complex

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