Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

Andrew D. Burrows; Christopher G. Frost; Mary F. Mahon; Paul R. Raithby; Catherine L. Renouf; Christopher Richardson; Anna J. Stevenson

doi:10.1039/C0CC00646G

Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

Andrew D. Burrows,*^a Christopher G. Frost,^a Mary F. Mahon,^a Paul R. Raithby,^a Catherine L. Renouf,^a Christopher Richardson^a^b and Anna J. Stevenson^a

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^a Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
E-mail: a.d.burrows@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 386529

^b School of Chemistry, University of Wollongong, Wollongong, Australia

Abstract

The Group 13 metal complexes [M(L²)₃], where M is Al or Ga and L² is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metal–organic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL²)₃(H₂L²)]Cl₄·EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

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Publication details

The article was received on 29 Mar 2010, accepted on 21 May 2010 and first published on 08 Jun 2010

Article type: Communication

DOI: 10.1039/C0CC00646G

Citation: Chem. Commun., 2010,46, 5067-5069

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Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

A. D. Burrows, C. G. Frost, M. F. Mahon, P. R. Raithby, C. L. Renouf, C. Richardson and A. J. Stevenson, Chem. Commun., 2010, 46, 5067
DOI: 10.1039/C0CC00646G
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Chemical Communications

Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

Abstract

Supplementary files

Publication details

Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

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