Issue 28, 2010
From the journal:

Chemical Communications

TEMPO reacts with oxygen-centered radicals under acidic conditions†

Riccardo Amorati,a   Gian Franco Pedulli,a   Derek A. Pratt*b  and  Luca Valgimigli*a  

* Corresponding authors

a Department of Organic Chemistry “A. Mangini”, University of Bologna, Via San Giacomo 11, 40126, Bologna, Italy
E-mail: luca.valgimigli@unibo.it
Fax: +39 051 2095688
Tel: +39 051 2095683

b Department of Chemistry, Queen's University, 90 Bader Crescent Lane, Kingston, Ontario, Canada K7L 3N6
E-mail: pratt@chem.queensu.ca
Fax: +1 613 533 6669
Tel: +1 613 533 3287

Abstract

In the presence of organic acids in organic media, 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) reacts with peroxyl radicals at nearly diffusion-controlled rates by proton-coupled electron transfer from the protonated nitroxide.

Graphical abstract: TEMPO reacts with oxygen-centered radicals under acidic conditions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC00547A
Article type
Communication
Submitted
23 Mar 2010
Accepted
07 May 2010
First published
11 Jun 2010

Chem. Commun., 2010,46, 5139-5141

Permissions

Request permissions

TEMPO reacts with oxygen-centered radicals under acidic conditions

R. Amorati, G. F. Pedulli, D. A. Pratt and L. Valgimigli, Chem. Commun., 2010, 46, 5139 DOI: 10.1039/C0CC00547A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements