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Issue 29, 2010
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Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

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Abstract

Cationic rhodium(I) complexes containing the flexible hemilabile phosphine ligand (3-ethoxypropyl)diphenylphosphine efficiently catalyzed the anti-Markovnikov oxidative amination of styrene in tetrahydrofurane at 80 °C to produce (E)-1-styrylpiperidine with turnover frequencies up to 75 h−1 with excellent enamine selectivity (96%).

Graphical abstract: Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

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Publication details

The article was received on 22 Mar 2010, accepted on 25 May 2010 and first published on 24 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC00525H
Citation: Chem. Commun., 2010,46, 5322-5324
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    Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

    M. V. Jiménez, J. J. Pérez-Torrente, M. I. Bartolomé, F. J. Lahoz and L. A. Oro, Chem. Commun., 2010, 46, 5322
    DOI: 10.1039/C0CC00525H

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