Issue 27, 2010
From the journal:

Chemical Communications

Testing the functional tolerance of the Piers–Rubinsztajn reaction: a new strategy for functional silicones†

John B. Grande,a   David B. Thompson,‡a   Ferdinand Gonzagaa  and  Michael A. Brook*a  

* Corresponding authors

a Department of Chemistry and Chemical Biology, McMaster University, 1280 Main St. W., Hamilton ON, Canada
E-mail: mabrook@mcmaster.ca
Fax: + 1 905 522 2509
Tel: + 1 905 525 9140 ext. 23483

Abstract

The Piers–Rubinsztajn reaction, involving B(C6F5)3-catalyzed siloxane formation from hydrosilanes + alkoxysilanes, is tolerant of a wide variety of functional groups, and provides a generic strategy for the preparation of structurally complex functional silicones.

Graphical abstract: Testing the functional tolerance of the Piers–Rubinsztajn reaction: a new strategy for functional silicones

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Article information

DOI
https://doi.org/10.1039/C0CC00369G
Article type
Communication
Submitted
13 Mar 2010
Accepted
24 Apr 2010
First published
28 May 2010

Chem. Commun., 2010,46, 4988-4990

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Testing the functional tolerance of the Piers–Rubinsztajn reaction: a new strategy for functional silicones

J. B. Grande, D. B. Thompson, F. Gonzaga and M. A. Brook, Chem. Commun., 2010, 46, 4988 DOI: 10.1039/C0CC00369G

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