Issue 24, 2010

Poly(β-alanoid-block-β-alanine)s: synthesis viacobalt-catalyzed carbonylative polymerization and self-assembly

Abstract

The titled diblock copolymers are synthesized via cobalt-catalyzed living carbonylative polymerization of N-alkylaziridines under moderate pressures followed by a deprotection step. The poly(β-alanine) block is solubilized by the poly(β-alanoid) block in chloroform and remains fully hydrogen-bonded in the form of a sheet-like assembly.

Graphical abstract: Poly(β-alanoid-block-β-alanine)s: synthesis via cobalt-catalyzed carbonylative polymerization and self-assembly

Supplementary files

Article information

Article type
Communication
Submitted
11 Mar 2010
Accepted
14 Apr 2010
First published
19 May 2010

Chem. Commun., 2010,46, 4273-4275

Poly(β-alanoid-block-β-alanine)s: synthesis via cobalt-catalyzed carbonylative polymerization and self-assembly

S. Lin, X. Yu, Y. Tu, H. Xu, S. Z. D. Cheng and L. Jia, Chem. Commun., 2010, 46, 4273 DOI: 10.1039/C0CC00324G

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