Jump to main content
Jump to site search

Issue 29, 2010
Previous Article Next Article

Ba8Co2Mn6ClO22, a quasi-1D hexagonal perovskite polytype containing new 8H-blocks

Author affiliations

Abstract

In this communication we report the synthesis and full structural characterization of the new phase Ba8Co2Mn6ClO22 formed of novel 8H-hexagonal perovskite blocks, a good example of the use of a multi-technique approach (combination of single crystal X-ray diffraction, micro-probe analysis and DFT calculations). Strikingly, the stabilization of original linear hexamers in the blocks is achieved by Mn/Co ordering in the octahedral and tetrahedral sites.

Graphical abstract: Ba8Co2Mn6ClO22, a quasi-1D hexagonal perovskite polytype containing new 8H-blocks

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Mar 2010, accepted on 02 Jun 2010 and first published on 16 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC00294A
Citation: Chem. Commun., 2010,46, 5271-5273
  •   Request permissions

    Ba8Co2Mn6ClO22, a quasi-1D hexagonal perovskite polytype containing new 8H-blocks

    M. Iorgulescu, H. Kabbour, N. Tancret, O. Mentré and P. Roussel, Chem. Commun., 2010, 46, 5271
    DOI: 10.1039/C0CC00294A

Search articles by author

Spotlight

Advertisements