Issue 27, 2010

py2P2S7: a bis(pyridine)adduct stabilized phosphorus sulfide

Abstract

The new phosphorus sulfide P2S7, stabilized as the bis(pyridinium) adduct, was obtained from the reaction of P4S10 and sulfur in pyridine, and could be isolated in the form of colourless block-shaped crystals which were characterized using single crystal X-ray diffraction. Coordination of pyridine is weak (d(P–N) = 187 pm) which is supported also by quantum chemical calculations.

Graphical abstract: py2P2S7: a bis(pyridine)adduct stabilized phosphorus sulfide

Supplementary files

Article information

Article type
Communication
Submitted
24 Feb 2010
Accepted
04 May 2010
First published
28 May 2010

Chem. Commun., 2010,46, 5024-5025

py2P2S7: a bis(pyridine)adduct stabilized phosphorus sulfide

C. Rotter, C. Evangelisti, S. Schönberger, T. M. Klapötke and K. Karaghiosoff, Chem. Commun., 2010, 46, 5024 DOI: 10.1039/C0CC00106F

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