Issue 23, 2010

Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

Abstract

Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.

Graphical abstract: Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2010
Accepted
09 Apr 2010
First published
12 May 2010

Chem. Commun., 2010,46, 4178-4180

Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

A. Serra-Muns, A. Guérinot, S. Reymond and J. Cossy, Chem. Commun., 2010, 46, 4178 DOI: 10.1039/C0CC00035C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements