Richard E. Smalley Institute for Nanoscale Science and Technology, Center for Biological and Environmental Nanotechnology, and Department of Chemistry, Rice University, Houston, Texas 77005, USA
Chem. Commun., 2010,46, 4764-4766
12 Feb 2010,
14 May 2010
First published online
02 Jun 2010
Two new fullerene amino acids have been prepared by dipolar addition to C60 of either the Boc- or Fmoc-Nα-protected azido amino acids derived from phenylalanine and lysine. UV-visible and CV studies indicate the as prepared amino acids are a mixture of 5,6-open (major product) and 6,6-closed (minor product) derivatives that may be readily separated.
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