Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane

Mehmet Zahmakıran; Mar Tristany; Karine Philippot; Katia Fajerwerg; Saim Özkar; Bruno Chaudret

doi:10.1039/C000419G

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Chemical Communications

Issue 17, 2010

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Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane

Mehmet Zahmakıran , Mar Tristany , Karine Philippot , Katia Fajerwerg , Saim Özkar and Bruno Chaudret

Chem. Commun., 2010, 46, 2938-2940

DOI: 10.1039/C000419G
Received 08 Jan 2010, Accepted 12 Feb 2010
First published on the web 10 Mar 2010

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The preparation of Ru(0) nanoclusters stabilized by 3-aminopropyltriethoxysilane and their characterization by a combination of complementary techniques are described. These new Ru(0) nanoclusters provide high activity and unprecedented reusability as a heterogeneous catalyst in the dehydrogenation of dimethylamine–borane.

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Experimental section; Fig. S1: ¹¹B NMR spectra of DMAB solution and the reaction solution at the end of the Ru(0)/APTS catalyzed dehydrogenation of DMAB, Fig. S2: H ₂/DMAB vs. time graph for the Ru(0)/APTS catalyzed dehydrogenation of DMAB for up to three catalytic runs
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Mehmet Zahmakıran
Mar Tristany
Karine Philippot
Katia Fajerwerg
Saim Özkar
Bruno Chaudret

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Chemical Communications

Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane

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