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Issue 21, 2010
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Organocatalytic asymmetric aza-Nazarov cyclization of an azirine

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Abstract

An unusual organocatalytic asymmetric cyclization of a ketoazirine that is accompanied by a kinetic resolution leads to 4-hydroxy-3-oxo-1,2,3,6-tetrahydropyridine-2-carboxylates in >99/1 er.

Graphical abstract: Organocatalytic asymmetric aza-Nazarov cyclization of an azirine

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The article was received on 05 Jan 2010, accepted on 14 Apr 2010 and first published on 28 Apr 2010


Article type: Communication
DOI: 10.1039/B927564A
Citation: Chem. Commun., 2010,46, 3774-3775
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    Organocatalytic asymmetric aza-Nazarov cyclization of an azirine

    N. Shimada, B. O. Ashburn, A. K. Basak, W. F. Bow, D. A. Vicic and M. A. Tius, Chem. Commun., 2010, 46, 3774
    DOI: 10.1039/B927564A

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