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Issue 20, 2010
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Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations

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Abstract

Two cyanide-bridged alternated 1 : 1 RuIII/MnIII complexes structurally characterized as single-chain containing co-crystallized bulk anions and cations have been successfully assembled from [Mn(TPP)(H2O)2]+ and [Ru(acac)2(CN)2] blocks. Systematic investigation of their magnetic properties reveals typical single-chain magnet (SCM) behaviors for both of them.

Graphical abstract: Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(iii)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(iii) containing co-crystallized bulk anions and cations

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Publication details

The article was received on 17 Dec 2009, accepted on 17 Feb 2010 and first published on 24 Mar 2010


Article type: Communication
DOI: 10.1039/B926710G
Citation: Chem. Commun., 2010,46, 3550-3552
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    Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations

    D. Zhang, L. Zhang, Y. Chen, H. Wang, Z. Ni, W. Wernsdorfer and J. Jiang, Chem. Commun., 2010, 46, 3550
    DOI: 10.1039/B926710G

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